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Ameen, Dana and Snape, Timothy J. 
ORCID: 0000-0003-2766-4491
(2015)
A Baker–Venkataraman retro-Claisen cascade delivers a novel alkyl migration process for the synthesis of amides.
Tetrahedron Letters, 56
(14).
pp. 1816-1819.
ISSN 00404039
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2015.02.077
Abstract
A simple extension of the carbamoyl Baker-Venkataraman rearrangement has been developed. If residual water in the reaction is not strictly excluded a Baker-Venkataraman retro-Claisen cascade takes place, giving amide products, in which an alkyl group apparently migrates between two functionalities of the substrate.
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